Completed funded project

Ceramic Sub Sea Systems (CS3)

Motivation

Components made of sintered stainless steel
© Fraunhofer-Centre HTL

Carbides have good wear resistance, compressive strength, fracture toughness and corrosion resistance, which qualifies them for use in the submarine industry, metal processing, automotive and chemical industries or in tool making. The most important hard metals consists of tungsten carbide (WC) with cobalt (Co) or nickel (Ni). The carbide provides hardness and wear resistance, while the metallic binder brings ductility and toughness to the composite. The properties of WC-based carbides can be adjusted over a wide range.

 

Objective

Results of the microstructure-property simulation of the modulus of elasticity of WC/Co as a function of WC volume fraction
© Fraunhofer-Centre HTL
Results of the microstructure-property simulation of the modulus of elasticity of WC/Co as a function of WC volume fraction

The target of the project was to develop a process for manufacturing components of complex geometries from hard metals using additive manufacturing. With the binder-jetting process, a cost-effective process suitable for small series was to be established. The challenge is that green parts produced with binder jetting have a very low green density. However, many industrial applications require dense components with a high tungsten carbide content > 85 wt.%. The densification should be achieved by a combination of liquid phase sintering or reactive melt infiltration. The Vickers hardness of the carbides produced in this way should be at least 1000 HV, the bending strength at least 1500 MPa.

 

Results

Production stages for a valve core with complex channel structures: CAD file (top left), printed green body (top right), horizontal section to illustrate the channels (bottom left) and sintered and reworked component (bottom right)
© Fraunhofer-Centre HTL
Production stages for a valve core with complex channel structures: CAD file (top left), printed green body (top right), horizontal section to illustrate the channels (bottom left) and sintered and reworked component (bottom right)
  • Binder-jetted components made from free-flowing carbide powders and adaptedprinting parameters
  • Optimised sintering and infiltration processes for 3D-printed hard metal bodies by in-situ investigations using the thermo-optical measuring device TOM_metal
  • Design and production of a valve insert with optimised flow channels based on 3D printing for off-shore use
  • Complex 3D-printed carbide components of the composition WC-Co 88-12, which could be densified by adapted of the sintering process
  • Microstructure property simulations which show the influence of different WC grain shapes and the co-binder content on the mechanical properties of WC-Co carbides  

Project Data

Project Duration 01.02.2016 - 31.12.2019
Sponsor Fraunhofer MaVo
Funding Amount 750,000 Euro

Project Partners

 

 

 

Fraunhofer HTL

Fraunhofer IKTS

Fraunhofer IPK

Fraunhofer IWM

Project Coordination Fraunhofer-Centre HTL
Project Management at the HTL
Dr. Sarig Nachum / Dr. Holger Friedrich